Issuing Body

Mississippi State University

Advisor

Shmulsky, Rubin

Committee Member

Shi, Q. Sheldon

Committee Member

Dubien, Janice

Committee Member

Grace, A. Laura

Committee Member

Schultz, P. Tor

Date of Degree

1-1-2010

Document Type

Dissertation - Open Access

Degree Name

Doctor of Philosophy

College

College of Forest Resources

Department

Department of Forest Products

Abstract

Lignocellulosic ethanol production currently uses expensive and harsh methods to extract wood sugars from small-diameter hardwood trees that otherwise would have little or no marketability. A byproduct that adds no value to the conversion process results, thus alternative methods are needed to make this fuel source cost-effective. This dissertation proposes only partially hydrolyzing southern hardwoods, extracting some polysaccharides for ethanol fermentation while leaving behind a modified wood material which could be used as furnish for manufacturing strand-based wood composites. Three treating solutions, 1% sulfuric acid, water, and 1% sodium hydroxide, along with untreated controls, were utilized in a partial hydrolysis at 150°C for 30 minutes. The treatments’ effects were measured by testing the mechanical, physical, surface, and durability properties of red oak, sweetgum, and yellow-poplar miniature beams (3 mm x 15 mm x 150 mm, t x r x l). These properties were then correlated to the polysaccharide content of the modified woods following treatment. All treatments provided a significant mass loss, with sweetgum’s mass loss being significantly greater than the other species. The initial effect of the partial hydrolysis on modulus of elasticity (MOE) showed water reduced MOE the least for each species. Sweetgum produced a higher reduction in MOE in all three solutions. Specific modulus was calculated to eliminate the density effect between the treatment combinations for measuring bending properties at oven-dry conditions. Sweetgum produced a lower SM in all treatments, and only the water treatment consistently reduced SM across all species. Wettablility was measured by dynamic contact angle analysis via the Wilhelmy plate technique in four probe liquids. Surface energies were then calculated by the geometric mean procedure. Acid and water treatments improved the wettability for all species. Alkaline treatment effects were species-specific. All treatments improved the surface energy of red oak. The AWPA E1-09 no-choice termite test determined mass loss due to Reticulitermes flavipes Kollar. Yellow-poplar averaged a significantly higher mass loss while wood treated in water or NaOH showed a higher degree of termite degradation compared to the controls. Polysaccharide content significantly correlated with mass loss due to treatment and specific modulus.

URI

https://hdl.handle.net/11668/15609

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