Mississippi State University
Bricka, R. Mark
Zappi, Mark E.
Keith, Jason M.
Other Advisors or Committee Members
French, W. Todd
Date of Degree
Dissertation - Open Access
Doctor of Philosophy
Dave C. Swalm School of Chemical Engineering
Tars have been identified as one of the major impurities associated with the utilization of biomass gasification fuel gas. Tars may result in blockages, plugging, corrosion and catalyst deactivation, leading to serious operational and maintenance problems during biomass gasification. Therefore, tar removal is essential to insure economic and effective fuel gas utilization. This study investigates the catalytic activity of zeolites, and nickel-supported zeolites for tar removal. Tests were conducted using a bench scale reactor and naphthalene as a model tar compound. Zeolites with varying pore sizes and acidity were tested to evaluate the effect of pore size and acidity on tar removal. Test results suggested that the catalytic activity increased with an increase in pore size and the number of acidic sites on the zeolite. The steam reforming ability of nickel towards naphthalene removal was evaluated by impregnating nickel on zeolites; this impregnation improved the activity of the catalysts significantly. Long term catalytic activity tests were performed, which showed that nickel supported ZY-30 and ZY-80 had the best naphthalene conversion, with naphthalene conversions of greater than 99%, followed by nickel- supported ZY-5.2, SiO2/Al2O3, and chabazite, respectively. This study also evaluated the catalytic activity of montmorillonite and nickel- supported montmorillonite as tar removal catalysts. Montmorillonite, and Ni-montmorillonite were tested for their efficiency in reforming tars. Also, the efficacy of nickel-supported montmorillonite catalyst was tested as a function of nickel content, reaction temperature, naphthalene loading, and the steam to carbon ratio. The results demonstrated that montmorillonite was catalytically active in removing naphthalene. In addition, Ni-montmorillonite had very high activity towards naphthalene removal via steam reforming, with removal efficiencies of greater than 99%. The activation energy was calculated for Ni-montmorillonite assuming first order kinetics and was found to be 84.5 kJ/mole. Long-term activity tests showed that the catalyst was active with naphthalene removal efficiencies of greater than 95%, which were maintained over a 97-hour test period. Very little loss of activity was observed with a drop in removal from 97 to 95%. The drop in catalytic activity was attributed primarily to a decrease in catalyst surface area, nickel sintering, and coke formation.
Buchireddy, Prashanth R., "Biomass Gasification: Catalytic Steam Reforming of Tars Using Nickel Supported Zeolites and Montmorillonite" (2014). Theses and Dissertations. 887.