Theses and Dissertations
ORCID
https://orcid.org/0000-0003-0053-2544
Issuing Body
Mississippi State University
Advisor
Wang, Kun
Committee Member
Gangishetty, Mahesh K.
Committee Member
Wipf, David O.
Date of Degree
8-8-2023
Document Type
Dissertation - Open Access
Major
Chemistry
Degree Name
Master of Science (M.S.)
College
College of Arts and Sciences
Department
Department of Chemistry
Abstract
The precise control of the resonance frequency of plasmonic nanostructures is critical and depends on the size, composition, shape, and dielectric nature of the environment. The ability to control the shape and size of nanomaterials acutely depends on the fabrication technique and material design. We used a cheap and scalable method known as nanosphere lithography (NSL) to fabricate plasmonic nano-prism (NP) on glass and indium tin oxide substrate (ITO). The methods involve substrate hydrophilicity treatment, polystyrene nanosphere masking, metal deposition, and mask removal. The array and specific morphology of the fabricated NP was established using scanning electron microscope (SEM) and atomic force microscope (AFM). Finally, we used UVVis spectroscopy to determine the plasmonic resonance frequencies of fabricated NP on different substrates. The results reported herein have potential applications in surface-enhanced Raman spectroscopy (SERS), and biosensing. We also used scanning tunneling microscope to obtain high spatial resolution images of supramolecular trigrams.
Recommended Citation
Ayinla, Ridwan Tobi, "Fabrication and imaging of highly ordered plasmonic Au nano-prism and self-assembled supramolecular nanostructure" (2023). Theses and Dissertations. 5917.
https://scholarsjunction.msstate.edu/td/5917