Theses and Dissertations
Issuing Body
Mississippi State University
Advisor
Toghiani, Rebecca
Committee Member
Toghiani, Hossein
Committee Member
Hill, Priscilla
Date of Degree
8-2-2003
Document Type
Graduate Thesis - Open Access
Major
Chemical Engineering
Degree Name
Master of Science
College
James Worth Bagley College of Engineering
Department
Dave C. Swalm School of Chemical Engineering
Abstract
The production of 7-tetradecene was examined. Properties for this compound were estimated using group contribution methods and compared to experimental data. Process simulation was used as a tool to identify competitive processing strategies. For reactive distillation, three different models were compared to determine the model complexity needed to describe the process: Model A, with the assumption of physical and chemical equilibrium; Model B, with kinetics described by a second order reaction and physical equilibrium; and Model C, a non-equilibrium stage model that accounts for mass transfer. A conceptual design was obtained with Model B and was checked with Model C, which described the process more accurately but was more difficult to converge. Since, Model A was easier to converge, it was used to predict process conversions at different pressures. Predictions favor working at 1 bar, due to the lower heat duty and the minimum stages required.
URI
https://hdl.handle.net/11668/20302
Recommended Citation
Serrano, Sandra Viviana Bennun, "Computer Simulation Studies for the Production of 7-Tetradecene by Reactive Distillation" (2003). Theses and Dissertations. 1150.
https://scholarsjunction.msstate.edu/td/1150