Theses and Dissertations
Issuing Body
Mississippi State University
Advisor
Skarke, Adam
Committee Member
Kirkland, Brenda
Committee Member
Gabitov, Rinat
Date of Degree
8-12-2016
Document Type
Graduate Thesis - Open Access
Major
Geology
Degree Name
Master of Science
College
College of Arts and Sciences
Department
Department of Geosciences
Abstract
Calcium carbonate minerals (CaCO3) are important for our understanding of past marine conditions as well as tools for constructing paleoclimate. However, very little experimental work has been done to determine the influence of oxygen depletion on the geochemistry of CaCO3. To determine how oxygen depletion affects elemental incorporation and partitioning, aragonite was grown inorganically in artificial seawater at pressures of 1 atm and 5 bars (0.1%CH4-N2 mixture). Solution of Na2CO3 was used to induce aragonite precipitation. N2 was bubbled through solution in order to minimize oxygen content and iron powder was used to trap remaining O2. Experimental products (aragonite and fluid) were analyzed with ICP-MS, and isotope ratio mass spectrometer. Results suggest that Eh affects incorporation of Mn, S, Cu, and V into aragonite. No methane oxidation was observed.
URI
https://hdl.handle.net/11668/20730
Recommended Citation
Mitchell, Jonney, "Precipitation of Aragonite under Anoxic Conditions: An Experimental Study" (2016). Theses and Dissertations. 3590.
https://scholarsjunction.msstate.edu/td/3590
Comments
aragonite||carbonates||partition coefficient||oxidation state