Theses and Dissertations
Issuing Body
Mississippi State University
Advisor
Toghiani, Hossein
Committee Member
Bricka, R. Mark
Committee Member
Toghiani, Rebecca K.
Date of Degree
4-30-2011
Document Type
Graduate Thesis - Open Access
Major
Chemical Engineering
Degree Name
Master of Science
College
James Worth Bagley College of Engineering
Department
Dave C. Swalm School of Chemical Engineering
Abstract
Nano-scaled carbons were produced by thermal treatment of pine wood chips and bio-char. The influence of temperature, heating rate, pyrolysis time, and type and flow rate of purge gas on the production of nano-carbons was investigated. Using TEM and SEM, different carbon-based nanomaterials were observed in the prepared samples. The effect of metal ion doping on the bio-char was also investigated. Highly functionalized nano carbonaceous materials were synthesized by low temperature hydrothermal carbonization (HTC) using glucose, sucrose, xylose, and cellulose. Carbon-encapsulated iron (Fe@C) core-shell particles were also synthesized by the HTC method and used as catalyst for Fischer-Tropsch synthesis to produce liquid hydrocarbons from syngas; it showed excellent activity. Nano-structured Co-Mo carbides over several nano-sized carbon materials were prepared using the carbothermal reduction and carbothermal hydrogen reduction methods. Nano-structured Co-Mo carbides derived from Vulcan® XC-72 were used as the catalyst to produce higher alcohols.
URI
https://hdl.handle.net/11668/17941
Recommended Citation
Yan, Qiangu, "Synthesis, Characterization and Catalytic Studies of Carbon-Based Nano Materials" (2011). Theses and Dissertations. 4193.
https://scholarsjunction.msstate.edu/td/4193
Comments
Nano carbons||Fischer-Tropsch synthesis (FTS)||catalyst||carbothermal hydrogen reduction (CHR)||carbothermal reduction (CR)||Co-Mo carbide||hydrothermal carbonization||treatment conditions||thermal treatment||biochar||pine wood||syngas||liquid fuels